Calculations and Measurements of the Dynamic Stark Effect in Hydrogen
نویسندگان
چکیده
A theory is given for the spectral profile of the first hydrogen Balmer line when the radiating neutral atom is under influence of both (quasi-) static and harmonically oscillating electric fields. Profiles, measured in a turbulent heating experiment, show a series of intensity maxima on the wings of the Balmer lines. If we assume a model for the spatial distribution of turbulent wave vectors, we can derive the fieldstrength and the direction of low-frequency (ion-acoustic) oscillations and the strength and frequency of high-frequency (Langmuir) oscillations.
منابع مشابه
Electrostatic fields near the active site of human aldose reductase: 1. New inhibitors and vibrational stark effect measurements.
Vibrational Stark effect spectroscopy was used to measure electrostatic fields in the hydrophobic region of the active site of human aldose reductase (hALR2). A new hALR2 inhibitor was designed and synthesized that contains a nitrile probe with a Stark tuning rate of 0.77 cm-1/(MV/cm). Mutations to amino acid residues in the vicinity of the nitrile functional group were selected based on electr...
متن کاملMeasurements of the radial profile of magnetic field in the Gas-Dynamic Trap using a motional Stark effect diagnostic
We have implemented a spectral motional Stark effect diagnostic for spatially localized measurements of magnetic field on the Gas-Dynamic Trap ~GDT! magnetic mirror device. A 7 A, 40 keV diagnostic neutral hydrogen beam was focused to a current density of 0.25 A/cm in the measurement volume, allowing achievement of a radial resolution of 4.5 cm by viewing the beam at 45° with a well-defined lig...
متن کاملDirect measurements of electric fields in weak OH···π hydrogen bonds.
Hydrogen bonds and aromatic interactions are of widespread importance in chemistry, biology, and materials science. Electrostatics play a fundamental role in these interactions, but the magnitude of the electric fields that support them has not been quantified experimentally. Phenol forms a weak hydrogen bond complex with the π-cloud of benzene, and we used this as a model system to study the r...
متن کاملInvestigation of vessels pressure effect on PEM electrolyzer performance by using a new OneDimensional Dynamic Model
In recent years energy shortage and environmental impacts due to consuming fossil fuels have led to developing renewable energy sources systems. Since these sources are not reliable and are usually time dependent, an energy storing system like hydrogen production is required. In this regard, PEM electrolyzer can be efficiently used to decompose liquid water into hydrogen and oxygen. Because of ...
متن کاملElectrochemical and Quantum Chemical Study of Vanillin as a Green Corrosion Inhibitor for AA6061 in NaCl Solution
The effect of vanillin on the corrosion behavior of AA6061 Al alloy in 3.5% NaCl solution wasinvestigated using potentiodynamic polarization and electrochemical noise (EN) techniques. Vanillinoffers interesting possibilities for corrosion inhibition due to its nontoxicity and high solubility inaqueous media. The best inhibition effect at 200 ppm vanillin was a marked characteristic of theinhibi...
متن کامل